Product ID:CHLORINATED HYDROCARBON PESTICIDES MIX 1, 41801
MSDS Date:01/11/1993
FSC:6840
NIIN:00N059186
MSDS Number: BXGNP

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

4,7-METHANOINDENE, 1,4,5,6,7,8,8-HEPTACHLORO-

CAS: 76-44-8

RTECS: PC0700000

Fraction By Weight: 0.0002%

OSHA PEL S, 0.5 PPM

ACGIH TLV: S, 0.05 PPM,A3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

40 MG/KG

RTECS: 9999999ZZ

ETHANE, 1,1-CICHLORO-2,2-BIS(P-CHLOROPHENYL)-;

CAS: 72-54-8

RTECS: KI0700000

Fraction By Weight: 0.001%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

113 MG/KG

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRICHLORO-2,2-BIS(P-CHLOROPHENYL)-; (4,4-DDT)

CAS: 50-29-3

RTECS: KJ3325000

Fraction By Weight: 0.001%

OSHA PEL S, 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

5,8-DIMETHANONAPHTHALENE,

CAS: 60-57-1

RTECS: IO1750000

Fraction By Weight: 0.0002%

OSHA PEL S, 0.25 MG/M3

ACGIH TLV: S, 0.25 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

46 MG/KG

RTECS: 9999999ZZ

CYCLOHEXANE, 1,2,3,4,5,6-HEXACHLORO-, GAMMA-ISOMER;

CAS: 58-89-9

RTECS: GV4900000

Fraction By Weight: 0.0002%

OSHA PEL S, 0.5 MG/M3

ACGIH TLV: 2, 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

5,8-DIMETHANONAPHTHALENE, 1,2,3,4,10,10-

CAS: 309-00-2

RTECS: IO2100000

Fraction By Weight: 0.0002%

OSHA PEL S, 0.25 MG/M3

ACGIH TLV: S, 0.25 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

39 MG/KG

RTECS: 9999999ZZ

5-NORBORNENE-2,3-DIMETHANOL, 1,4,5,6,7,7-HEXACHLORO-,

CAS: 959-98-8

RTECS: RB9275100

OSHA PEL S, 0.1 MG/M3

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

76 MG/KG

RTECS: 9999999ZZ

5-NORBORNENE-2,3-DIMETHANOL, 1,4,5,6,7,7,-HEXACHLORO-CYCLIC

CAS: 1031-07-8

RTECS: RB9150000

Fraction By Weight: 0.001%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

9750 MG/KG

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 99-100%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:BURNS EYES, IRRITATES RESPIRATORY
TRACT. IRRITATES SKIN, DERMATITIS, HEADACHE, DIZZINESS, GI
DISTURBANCES, DEPRESSES CENTRAL NERVOUS SYSTEM, CONVULSIONS,
ERYTHEMA, ECZEMA, CONJUNCTIVITIS, AND CORNEAL EROSION. SOME INGS @
LOW CONC (BELOW OSHA-HCS THRESHOLDS). CLASSIFIED BY IARC AS A CLASS
2B CARCINOGEN (MFR).
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MIN. CONT MD. SKIN:PROMPLY
WASH W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG.
INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS, GIVE ARTF RESP. CONT
MD. INGEST:NEV ER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. NEVER
TRY TO MAKE AN UNCON PERSON VOMIT. GIVE LG AMTS OF WATER. PRESS
FINGERS TO BACK OF TONGUE TO INDUCE VOMIT. IMMED CONT MD.

Flash Point Method:CC
Flash Point:-2F,-19C
Lower Limits:2.6%
Upper Limits:13.0%
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS FORM EXPLO MIXS W/AIR. CNTNRS MAY
EXPLODE UNDER FIRE CNDTNS. TOX VAPS FORMED WHEN MATL IS HEATED TO
DECOMP:HYDROGEN CHLORIDE, OXIDES OF SULFUR.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM IGNITION SOURCES. AVOID EYE OR SKIN CONTACT. AVOID
BREATHING VAPORS.
Other Precautions:MAL IS INTENDED FOR R&D USE ONLY & MAY NOT BE USED
FOR DRUG, HOUSEHOLD/OTHER PURPOSES. IT IS SUBJECT TO TSCA REGS @CFR
40 720.36 WHICH DEAL W/EXEMPTION OF CHEMS USED IN RESEARCH &
DEVELOPMENT FROM PMN (PREMFR NOTIFICATION) REQS. (SUPP DATA)

Respiratory Protection:WEAR NIOSH/MSHA APPROVED SELF CONTAINED
BREATHING APPARATUS.
Ventilation:USE ONLY IN EXAUST HOOD.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC:IN ADDITION, THE BURDEN OF SAFE USE OF THE MATERIAL RESTS
WITH YOU AND, THEREFORE, IT SHOULD BE HANDLED ONLY BY QUALIFIED
PERSONS TRAINED IN LABORATORY PROCEDURES AND GOOD SAFETY PRACTICES.

Boiling Pt:B.P. Text:133F,56C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:181 @ 20C
Vapor Density:2
Spec Gravity:0.792 G/ML
Evaporation Rate & Reference:14.4 (BUTYL ACETATE=1)
Solubility in Water:100
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & BASES, OXIDIZING AGENTS, AMINES, OXYGEN, ALKANOLAMINES,
HALOGENS, ALDEHYDES, AMMONIA & CHLORINATED CMPDS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, OXIDES OF SULFUR.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS
WHEN EMPTIED. CONTAINERS RETAIN PRODUCT RESIDUES:HANDLE AS IF THEY
WERE FULL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.